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PEDOT:PSS/silicon solar cell built at room temperature with 10.1% efficiency – pv magazine International

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Japanese researchers have produced a heterojunction (HJT) photo voltaic cell with silicon and a polymer materials often known as PEDOT:PSS below room temperature circumstances. It has an effectivity of 10.1%, an open circuit voltage of 0.57 V, a short-circuit present density of 33.3 mA/cm2, and a fill issue of 0.53.

Scientists from Kyoto College in Japan have developed an organic-inorganic hybrid HJT photo voltaic cell with out utilizing a vacuum or excessive temperature processes. They used PEDOT:PSS, a polymer identified for its low price and simple preparation properties, as a gap transport layer in a silicon (Si) heterojunction cell.

To type the electrodes with out utilizing costly processes similar to display printing, electroless plating, and vacuum evaporation, teachers used a extremely conductive silver (Ag) ink agent to coat semiconductor supplies as electrodes. Their photo voltaic cell manufacturing course of consists of solely three coating processes: coatings on a PEDOT:PESS layer on a naked Si wafer, on a high Ag electrode on the PEDOT:PSS layer, and on a backside Ag electrode on the again floor of the Si wafer.

The researchers then investigated the optimum course of circumstances and sequence that maximized the photo voltaic cell’s efficiency. They discovered the perfect outcomes for cells made utilizing a primary moist hydrofluoric acid remedy to take away the native oxide layer on the Si floor, then the coating on the again of the Si wafer, adopted by immersion of the Si wafer in deionized water, then cowl the PEDOT : PSS layer, and eventually cowl the highest of the wafer.

After this course of, the staff says it discovered “a drastic change in cell effectivity throughout the immersion time [of the wafer in deionized water,] the place too shallow or extreme oxidation of the Si floor can severely harm the cell.” The scientists discovered the optimum time interval for this course of to be one minute and the perfect rotation pace for spin coating of PEDOT:PSS at 5,000 rpm.

A lab-scale of 8 mm2 produced below these circumstances exhibits a conversion effectivity of 10.1%, an open-circuit voltage of 0.57 V, a short-circuit present density of 33.3 mA/cm2and a fill issue of 0.53.

The lecturers mentioned that the effectivity worth is much from the state-of-the-art PEDOT:PSS/Si HJT photo voltaic cells “as a result of extreme restriction of the method situation… resistivity.”

Nonetheless, the scientists famous that their manufacturing technique “may result in handy, low-cost, high-throughput photovoltaic gadget manufacturing, notably helpful to be used in growing nations and areas of schooling. “

They shared their findings in “An all ambient, room temperature-processed photo voltaic cell from a naked silicon wafer,” which was lately revealed in PNAS Nexus.

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