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All-perovskite tandem solar cell with 28.5% efficiency – pv magazine International


A Chinese language analysis group has developed an all-perovskite photo voltaic cell with a 3D/3D double-layer perovskite heterostructure that reportedly ensures higher cost extraction. The gadget achieved an open-circuit voltage of two.112 V, a short-circuit present of 6.5 mA cm-2, and a outstanding fill issue of 81.9%.

Researchers at Nanjing College in China have developed an all-perovskite tandem photo voltaic cell that reportedly reveals low interfacial non-radiative recombination and improved cost extraction.

All-perovskite tandem cells – the place two completely different perovskite cells are stacked on high of one another – promise efficiencies just like tandem perovskite-silicon gadgets, greater than the 30% mark, with higher flexibility, lighter weight, and a decrease setting. impact than applied sciences that depend on silicon wafers.

“All perovskite tandem photo voltaic cells constructed on broad/slim bandgap perovskite cells have some great benefits of excessive effectivity and low price, which is a crucial improvement path of the subsequent era of photovoltaic know-how,” the lead creator of the analysis crew, Hairen Tan, mentioned. pv journal. “Our all-perovskite tandem photo voltaic cells can be utilized in energy station energy era, rooftop photovoltaic, water catalytic decomposition, carbon dioxide catalytic decomposition, and house purposes as a result of their excessive open circuit voltage and excessive effectivity.”

The scientists additionally defined that within the beforehand constructed all perovskite tandem perovskite gadgets suffered from low open-circuit voltage and filling issue as a result of excessive defect density on the floor of the blended slim bandgap perovskite movies primarily based on lead and tin (Pb-Sn) , which trigger severe non-radiation recombination loss on the interface between the perovskite absorber and the buckminsterfullerene (C60) electron transport layer (ETL).

“It’s a widespread technique to cut back the interface recombination loss in perovskite cells by depositing a two-dimension (2D) perovskite layer on the perovskite floor by resolution post-treatment to kind a 2D/3D heterojunction construction,” Tan mentioned. “Nevertheless, the 2D perovskite obtained by the post-treatment resolution has poor uniformity (layer n worth is tough to regulate) and low conductivity, which isn’t good on the interface for transport and extraction of carriers.”

To resolve these challenges, Tan’s crew designed a novel 3D/3D double-layer perovskite heterostructure. Utilizing a mixture of vacuum evaporation and resolution processing, a 3D pure lead wide-bandgap perovskite movie was grown on a Pb-Sn blended slim bandgap perovskite movie.

“The 3D pure lead wide-bandgap perovskite varieties a Sort-II heterojunction construction with a slim bandgap perovskite, which promotes the withdrawal of cost carriers from the perovskite absorption layer to the electron transport layer, decreasing the interface recombination loss between perovskite / C60, and might enhance the open circuit voltage, fill issue and effectivity of photo voltaic cells,” defined Tan.

The photo voltaic cell achieves an influence conversion effectivity of 28.5%, an open-circuit voltage of 2.112 V, a short-circuit present of 6.5mA cm-2, and a fill issue of 81.9%, with the Japan Electrical Security and Atmosphere Expertise Laboratories confirming a strong effectivity of 28.0%. “The encapsulated tandem gadgets retain 90% of their preliminary efficiency after 600 hours of steady operation underneath simulated one-sun illumination,” the researchers mentioned.

The Chinese language crew additionally created a cell with a big space of 1.05 cm2, and its effectivity reached 26.9%.

The teachers described the gadget within the examine as “All-perovskite tandem photo voltaic cells with 3D/3D bilayer perovskite heterojunction,” revealed in NATURE. Wanting forward, they are saying one thing electrical and optical losses ought to be additional investigated in lFOR essentially the most half THE TREES potential on all-perovskite tandem photo voltaic cells. “Potential approaches to handle optical loss embody decreasing optical reflection by directing gentle, utilizing extra clear entrance electrodes and gap transport materials, and exploring thicker narrower bandgaps. perovskite absorber layers,” they concluded.

Some researchers at Nanjing College lately developed an all-perovskite tandem photo voltaic cell with an effectivity of 24.2%.

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