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New Method Addresses Problem With Perovskite Solar Cells


NREL Researchers Supply Improvement Methodology That Improves Effectivity, Resilience

A brand new methodology of producing perovskite photo voltaic cells solves earlier issues and supplies gadgets with excessive effectivity and glorious stability, researchers on the Nationwide Renewable Power Laboratory (NREL) reported within the subject of the journal Science.

The event of steady and environment friendly perovskites primarily based on a wealthy combination of bromine and iodine is taken into account crucial for the event of tandem photo voltaic cells. The 2 parts, nonetheless, are inclined to separate when uncovered to mild and warmth and subsequently restrict the voltage and sturdiness of a photo voltaic cell.

“This new improvement methodology can stop part separation,” stated Kai Zhu, a senior scientist at NREL, principal investigator of the venture, and lead creator of the brand new paper ” Compositional texture engineering for extremely steady wide-bandgap perovskite photo voltaic cells.” His co-authors from NREL are Qi Jiang, Jinhui Tong, Rebecca Scheidt, Amy Louks, Robert Tirawat, Axel Palmstrom, Matthew Hautzinger , Steven Harvey, Steve Johnston, Laura Schelhas, Bryon Larson, Emily Warren, Matthew Beard, and Joseph Berry.

Different researchers concerned are on the College of Toledo.

The brand new methodology addresses that drawback and produces a wide-bandgap photo voltaic cell with an effectivity higher than 20% and a 1.33-volt photovoltage and little change in effectivity over 1,100 hours of steady operation. at excessive temperatures. With this new methodology, an all-perovskite tandem cell obtained an effectivity of 27.1% with a excessive photovoltage of two.2 volts and good operational stability.

Within the tandem cell, the slender bandgap layer is positioned on high of the vast bandgap layer. The distinction in bandgaps permits for extra photo voltaic spectrum to be captured and transformed into electrical energy.

Perovskite refers to a crystalline construction fashioned by depositing chemical compounds on a substrate. A excessive focus of bromine causes quicker crystallization of the perovskite movie and sometimes results in defects that cut back the efficiency of a photo voltaic cell. Numerous methods have been tried to mitigate these points, however the stability of vast bandgap perovskite photo voltaic cells continues to be thought of inadequate.

The newly developed methodology builds on work that Zhu and his colleagues printed earlier this yr that reverse-engineered a typical perovskite cell. Utilizing this inverted architectural construction permits researchers to extend effectivity and stability and simply combine tandem photo voltaic cells.

The NREL-led staff used the identical structure and moved away from the standard method of creating perovskites. The normal methodology makes use of an antisolvent utilized to the chemical crystals to create a uniform perovskite movie. The brand new methodology depends on so-called gasoline quenching, the place a stream of nitrogen is blown by chemical compounds. The consequence addresses the issue of separating bromine and iodine, leading to a perovskite movie with improved construction and optoelectronic properties.

The antisolvent methodology permits crystals to develop quickly and uniformly throughout the perovskite movie, crowding one another and resulting in defects the place grain boundaries meet. The gasoline quenching course of, when utilized in perovskite chemical compounds with excessive bromine, forces the crystals to develop collectively, tightly packed from high to backside, in order that they grow to be like a single grain and cut back the variety of defects. The highest-down progress methodology varieties a gradient construction, with extra bromine close to the floor and fewer within the bulk of the cell. The gas-quench methodology is statistically extra reproducible than the antisolvent methodology.

The researchers achieved an effectivity exceeding 20% ​​for the vast bandgap layer and operational stability with lower than 5% degradation in 1,100 hours. Mixed with the decrease cell, the machine reaches a 27.1% effectivity rating.

The researchers additionally examined argon and air because the drying gasoline with comparable outcomes, indicating that the gasoline quenching methodology is a basic methodology for enhancing the efficiency of vast bandgap perovskite photo voltaic cells.

The brand new progress methodology exhibits the potential of high-performance all-perovskite tandem gadgets and advances the event of different perovskite-based tandem architectures akin to these with silicon.

The US Division of Power’s Workplace of Photo voltaic Power Applied sciences funded the analysis.

Courtesy of NREL, the US Division of Power’s main nationwide laboratory for renewable power and power effectivity analysis and improvement. NREL is operated for DOE by the Alliance for Sustainable Power LLC.


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