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Perovskite solar cell achieves 24.3% efficiency, high stability via binary mixed hole transport layer – pv magazine International


Chinese language researchers have constructed a gap transport layer with a blended binary configuration combining the polymer Regioregular poly(3-hexylthiophene) (P3HT) and Spiro-OMeTAD. They used it to create a perovskite photo voltaic cell that was capable of retain 90% of its preliminary effectivity after 1,200 hours of storage in a darkish surroundings.

A gaggle of researchers led by the Chinese language Academy of Sciences (CAS) has constructed a perovskite photo voltaic cell based mostly on a binary blended gap transport layer (HTL) that reportedly provides higher efficiency than HTLs that depend on generally used hygroscopic dopants. .

“These dopants are reported to degrade machine stability attributable to their hygroscopic nature and dopant-induced ion migration, which promotes perovskites degradation,” the scientists stated.

They make HTL utilizing the polymer Regioregular poly(3-hexylthiophene) (P3HT) and Spiro-OMeTAD in a blended binary configuration, which they declare provides higher safety of the perovskite absorber used within the cell because of the hydrophobicity of P3HT. “P3HT not solely exhibits the next diploma of molecular order but additionally exhibits a most popular ‘face-on’ orientation, i.e., the P3HT molecules are parallel to the substrate, with extra constructive impact on opto-electronic properties and cost transportability,” they defined.

The Chinese language workforce constructed the photo voltaic cell utilizing an indium tin oxide (ITO) substrate, a tin(IV) oxide (SnO).2) electron transport layer (ETL), a perovskite layer, the proposed HTL, molybdenum oxide (MoOx) buffer layer, and a gold (Au) metallic contact.

Lecturers examined the efficiency of a number of photo voltaic cells developed with this design and with an lively space of ​​0.08 cm2 by a photo voltaic simulator with a 450 W Xenon lamp and a Keithley 2400 supply meter below normal gentle situations.

The champion machine achieved an influence conversion effectivity of 24.30% and an authorized effectivity of 24.22%. It additionally achieves an open-circuit voltage of 1.18 V, a short-circuit present density of 24.94 mA cm-2, and a fill issue of 82.51%. The cell was additionally capable of retain 90% of its preliminary effectivity after 1,200 hours of storage in a darkish surroundings.

“A profitable modification of the standard Spiro-OMeTAD HTL was demonstrated by incorporating the hydrophobic polymeric P3HT into the Spiro-OMeTAD movie to enhance the effectivity and stability of perovskite photo voltaic cells,” the group concluded. “We consider this technique will pave the best way for the event of low-cost, environment friendly and sturdy perovskite photo voltaic cells.”

Scientists current their findings within the examine “Binary Gap Transport Layer Allows Steady Perovskite Photo voltaic Cells with PCE Larger than 24%,” lately revealed in DeCarbon.

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